David Stephen Arputharaj (2023) A novel Cadmium metal-organic framework with exceptional nonlinear optical properties: Unveiling anisotropic charge transport and optical limiting behavior. A novel Cadmium metal-organic framework with exceptional nonlinear optical properties: Unveiling anisotropic charge transport and optical limiting behavior. ISSN 2211-7156

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Abstract

A novel non-centrosymmetric Cadmium Metal-Organic Framework (Cd-MOF) crystal with chemical formula
CdC8N8H14O2S4 was synthesized and characterized. The band structure and optical limiting properties of the Cd-
MOF were investigated using Band structure calculations and Optical limiting studies. The band structure
analysis showed that the crystal displayed a larger, highly dispersive band, highlighting significant anisotropic nchannel
charge carrier mobility. The optical limiting study demonstrated that the Cd-MOF exhibited Reverse
Saturable Absorption (RSA) behaviour with an optical limiting threshold value of 1094 kW/cm2. The NLO
behaviour of the Cd-MOF provides a promising potential for its application in NLO devices.

Item Type: Article
Additional Information: www.sciencedirect.com/journal/results-in-chemistry
Uncontrolled Keywords: Non-Centrosymmetric Cadmium Metal-Organic Framework (Cd-MOF) Band Structure Calculations Optical Limiting
Divisions: PSG College of Arts and Science > Department of Physics
Depositing User: Dr. B Sivakumar
Date Deposited: 22 Apr 2024 07:48
Last Modified: 22 Apr 2024 07:48
URI: https://ir.psgcas.ac.in/id/eprint/2139

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