Krishnamoorthy Bellie Sundaram (2025) Structural Preferences and Applications of Ruthenium-Porphyrin complexes - A Mini Review. Structural Preferences and Applications of Ruthenium-Porphyrin complexes - A Mini Review, 25 (10). pp. 495-504. ISSN 0023:4923

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Abstract

: Ruthenium complexes are known in huge numbers and possesses diverse structural features
and wide range of applications. This is due to the ability of ruthenium to form complexes with different
oxidation states like the common +2, +3, +4. Other oxidation ststes of ruthenium like +6 and +7, +8
also possible. Here we have reviewed the ruthenium-porphyrin complexes with different oxidation of
ruthenium like Ru(II), Ru(III) and Ru(IV). The synthesis, geometrical, electronic structure, spectral
properties and reactivities of important ruthenium-porphyrin complexes are covered. The octahedral
geometry around ruthenium with axially disposed ligands like in these ruthenium porphyrin complexes
with ligands like N(Ph)2 (1), NH3 (2), PH3 (3) and AsH3 (4), F (5), Cl (6), Br (7), I (8) have also been
confirmed by theoretical DFT (BP86/Def2-TZVP) investigations. Due to the important applications of
ruthenium-porphyrin complexes like in cancer chemotherapy through photodynamic therapy of like
Thus this quantum chemical study can lead to design and find out the better ruthenium-porphyrin
complexes with different ligands.

Item Type: Article
Uncontrolled Keywords: Ruthenium; Porphyrin;Ru(II); Ru(III); Ru(IV); Cancer Chemotherapy; Catalysis;
Divisions: PSG College of Arts and Science > Department of Chemistry
Depositing User: Dr. B Sivakumar
Date Deposited: 13 Mar 2026 04:33
Last Modified: 13 Mar 2026 04:33
URI: https://ir.psgcas.ac.in/id/eprint/2704

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